SYNTHESIS OF ORGANIC DEUTERIUM COMPOUNDS: IV. METHYL-d3 BROMIDE

synthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate

در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...

comparison of catalytic activity of heteropoly compounds in the synthesis of bis(indolyl)alkanes.

heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...

Methyl bromide alternatives evaluated

Methyl bromide under fire.

Methyl Bromide under Fire Methyl bromide is one of the most widely used pesticides in the world, a broad-spectrum fumigant effective in controlling insects, nematodes, fungi, and bacteria. Methyl bromide is also highly toxic to humans. In December 1993, the EPA listed methyl bromide as a stratospheric ozone-depleting substance subject to phase-out. The final rule, issued 1 January 1994, freezes...

Methyl bromide poisoning.

Methyl bromide is a highly volatile liquid which disperses rapidly and readily. As a fumigant it ranks amongst the most efficient because of its extremely effective penetrating power and absence of fire or explosion hazard. It is, unfortunately, highly toxic and poisoning occurs readily in circumstances of careless or inadvertent exposure. Before 1940, only 42 cases of methyl bromide poisoning ...